| Rk | Player | W - L | W% |
| 1 | Justine Henin(BEL) | 63 - 4 | 0.940 |
| 2 | Lindsay Davenport(USA) | 13 - 1 | 0.929 |
| 3 | Venus Williams(USA) | 50 - 10 | 0.833 |
| 4 | Maria Sharapova(RUS) | 40 - 11 | 0.784 |
| 5 | Serena Williams(USA) | 35 - 10 | 0.778 |
| 6 | Kim Clijsters(BEL) | 14 - 4 | 0.778 |
| 7 | Anna Chakvetadze(RUS) | 59 - 20 | 0.747 |
| 8 | Jelena Jankovic(SRB) | 72 - 25 | 0.742 |
| 9 | Ana Ivanovic(SRB) | 51 - 18 | 0.739 |
| 10 | Agnes Szavay(HUN) | 28 - 10 | 0.737 |
| 11 | Svetlana Kuznetsova(RUS) | 55 - 20 | 0.733 |
| 12 | Tatiana Golovin(FRA) | 46 - 18 | 0.719 |
| 13 | Nicole Vaidisova(CZE) | 35 - 14 | 0.714 |
| 14 | Elena Dementieva(RUS) | 41 - 18 | 0.695 |
| 15 | Pauline Parmentier(FRA) | 9 - 4 | 0.692 |
| 16 | Vera Zvonareva(RUS) | 30 - 14 | 0.682 |
| 17 | Daniela Hantuchova(SVK) | 52 - 26 | 0.667 |
| 18 | Shahar Peer(ISR) | 44 - 22 | 0.667 |
| 19 | Nadia Petrova(RUS) | 38 - 19 | 0.667 |
| 20 | Dinara Safina(RUS) | 43 - 22 | 0.662 |
| 21 | Victoria Azarenka(BLR) | 30 - 16 | 0.652 |
| 22 | Amelie Mauresmo(FRA) | 28 - 15 | 0.651 |
| 23 | Martina Hingis(SUI) | 24 - 13 | 0.649 |
| 24 | Patty Schnyder(SUI) | 45 - 25 | 0.643 |
| 25 | Na Li(CHN) | 23 - 13 | 0.639 |
| 26 | Virginie Razzano(FRA) | 35 - 20 | 0.636 |
| 27 | Sybille Bammer(AUT) | 43 - 25 | 0.632 |
| 28 | Lucie Safarova(CZE) | 29 - 17 | 0.630 |
| 29 | Milagros Sequera(VEN) | 13 - 8 | 0.619 |
| 30 | Marion Bartoli(FRA) | 47 - 31 | 0.603 |
| 31 | Sania Mirza(IND) | 30 - 20 | 0.600 |
| 32 | Tathiana Garbin(ITA) | 25 - 17 | 0.595 |
| 33 | Sara Errani(ITA) | 10 - 7 | 0.588 |
| 34 | Agnieszka Radwanska(POL) | 27 - 19 | 0.587 |
| 35 | Raluca Olaru(ROU) | 14 - 10 | 0.583 |
| 36 | Alona Bondarenko(UKR) | 32 - 24 | 0.571 |
| 37 | Flavia Pennetta(ITA) | 31 - 25 | 0.554 |
| 38 | Emilie Loit(FRA) | 26 - 21 | 0.553 |
| 39 | Gisela Dulko(ARG) | 28 - 23 | 0.549 |
| 40 | Francesca Schiavone(ITA) | 29 - 24 | 0.547 |
| 41 | Katarina Srebotnik(SLO) | 29 - 24 | 0.547 |
| 42 | Mara Santangelo(ITA) | 28 - 24 | 0.538 |
| 43 | Julia Vakulenko(UKR) | 22 - 19 | 0.537 |
| 44 | Anabel Medina Garrigues(ESP) | 26 - 24 | 0.520 |
| 45 | Maria Kirilenko(RUS) | 29 - 27 | 0.518 |
| 46 | Samantha Stosur(AUS) | 17 - 16 | 0.515 |
| 47 | Shuai Peng(CHN) | 19 - 19 | 0.500 |
| 48 | Dominika Cibulkova(SVK) | 17 - 17 | 0.500 |
| 49 | Tamira Paszek(AUT) | 15 - 15 | 0.500 |
| 50 | Karin Knapp(ITA) | 14 - 14 | 0.500 |
| 51 | Akgul Amanmuradova(UZB) | 8 - 8 | 0.500 |
| 52 | Eleni Daniilidou(GRE) | 27 - 29 | 0.482 |
| 53 | Elena Vesnina(RUS) | 20 - 22 | 0.476 |
| 54 | Meilen Tu(USA) | 20 - 22 | 0.476 |
| 55 | Nathalie Dechy(FRA) | 17 - 19 | 0.472 |
| 56 | Alicia Molik(AUS) | 18 - 21 | 0.462 |
| 57 | Michaella Krajicek(NED) | 21 - 25 | 0.457 |
| 58 | Akiko Morigami(JPN) | 16 - 20 | 0.444 |
| 59 | Caroline Wozniacki(DEN) | 12 - 15 | 0.444 |
| 60 | Virginia Ruano Pascual(ESP) | 11 - 14 | 0.440 |
| 61 | Meghann Shaughnessy(USA) | 18 - 23 | 0.439 |
| 62 | Lourdes Dominguez Lino(ESP) | 17 - 22 | 0.436 |
| 63 | Edina Gallovits-Hall(ROU) | 9 - 12 | 0.429 |
| 64 | Camille Pin(FRA) | 17 - 23 | 0.425 |
| 65 | Laura Granville(USA) | 11 - 15 | 0.423 |
| 66 | Vania King(USA) | 16 - 22 | 0.421 |
| 67 | Yaroslava Shvedova(KAZ) | 10 - 14 | 0.417 |
| 68 | Ai Sugiyama(JPN) | 17 - 24 | 0.415 |
| 69 | Nicole Pratt(AUS) | 11 - 17 | 0.393 |
| 70 | Kateryna Bondarenko(UKR) | 12 - 19 | 0.387 |
| 71 | Yung-Jan Chan(TPE) | 10 - 16 | 0.385 |
| 72 | Aiko Nakamura(JPN) | 13 - 21 | 0.382 |
| 73 | Roberta Vinci(ITA) | 11 - 18 | 0.379 |
| 74 | Lilia Osterloh(USA) | 7 - 12 | 0.368 |
| 75 | Martina Muller(GER) | 16 - 28 | 0.364 |
| 76 | Catalina Castano(COL) | 12 - 21 | 0.364 |
| 77 | Olga Savchuk(UKR) | 5 - 9 | 0.357 |
| 78 | Anastasia Rodionova(AUS) | 11 - 20 | 0.355 |
| 79 | Sofia Arvidsson(SWE) | 6 - 11 | 0.353 |
| 80 | Vasilisa Bardina(RUS) | 8 - 15 | 0.348 |
| 81 | Aleksandra Wozniak(CAN) | 8 - 16 | 0.333 |
| 82 | Angelique Kerber(GER) | 6 - 12 | 0.333 |
| 83 | Olga Puchkova(RUS) | 12 - 25 | 0.324 |
| 84 | Maria Elena Camerin(ITA) | 9 - 19 | 0.321 |
| 85 | Tsvetana Pironkova(BUL) | 7 - 15 | 0.318 |
| 86 | Julia Schruff(GER) | 6 - 13 | 0.316 |
| 87 | Jill Craybas(USA) | 12 - 27 | 0.308 |
| 88 | Tatiana Poutchek(BLR) | 7 - 16 | 0.304 |
| 89 | Aravane Rezai(FRA) | 8 - 21 | 0.276 |
| 90 | Eva Birnerova(CZE) | 5 - 14 | 0.263 |
| 91 | Iveta Melzer(CZE) | 6 - 17 | 0.261 |
| 92 | Severine Beltrame(FRA) | 9 - 26 | 0.257 |
| 93 | Sandra Kloesel(GER) | 4 - 13 | 0.235 |
| 94 | Tiantian Sun(CHN) | 5 - 17 | 0.227 |
| 95 | Anna-Lena Groenefeld(GER) | 4 - 15 | 0.211 |
| 96 | Alina Jidkova(RUS) | 2 - 8 | 0.200 |